摘 要
随着环保意识提升，绿色化学成为研究热点，特别是绿色溶剂在芳香族化合物合成中的应用。本研究探讨了水、离子液体和超临界二氧化碳等绿色溶剂对合成效率和产物纯度的影响，旨在为绿色化学提供理论和实践指导。研究发现，水在某些反应中反应速率和产物纯度较高，离子液体在特定反应中表现出优越性，而超临界二氧化碳在高温高压下能提高反应选择性和产率。优化反应条件和溶剂选择可减少副产物，提高经济性和环保性。研究还结合中国化工产业现状，提出适合国情的绿色溶剂应用策略，如推广水溶剂应用和推荐使用离子液体及超临界二氧化碳。这些策略有助于推动中国化工产业绿色转型和可持续发展。本研究揭示了不同绿色溶剂的优缺点和适用范围，为绿色化学发展提供新思路和方法，并结合中国实际提出的应用策略具有重要现实意义和推广价值。
关键词：绿色溶剂；芳香族化合物合成；可持续发展；离子液体；超临界二氧化碳
Abstract
With the promotion of environmental awareness, green chemistry has become a research hotspot, especially the application of green solvents in the synthesis of aromatic compounds. This study explored the effects of green solvents such as water, ionic liquids and supercritical carbon dioxide on the synthesis efficiency and product purity, aiming to provide theoretical and practical guidance for green chemistry. It is found that water has high reaction rate and product purity in some reactions, ionic liquid shows superiority in specific reactions, and supercritical carbon dioxide can improve the reaction selectivity and yield at high temperature and high pressure. Optimizing reaction conditions and solvent selection can reduce by-products and improve economy and environmental protection. In combination with the current situation of China's chemical industry, the research also puts forward green solvent application strategies suitable for national conditions, such as promoting the application of water solvent and recommending the use of ionic liquid and supercritical carbon dioxide. These strategies will help to promote the green transformation and sustainable development of China's chemical industry. This study reveals the advantages and disadvantages of application and application scope of different green solvents, provides new ideas and methods for the development of green chemistry, and the application strategies combined with China are of great practical significance and promotion value.
Key Words：Green solvent; Synthesis of aromatic compounds; Sustainable development; Ionic liquid; Supercritical carbon dioxide
目 录
摘 要 I
Abstract II
第1章 绪论 1
1.1 研究背景和意义 1
1.2 研究目的和内容 1
第2章 绿色溶剂的定义与分类 3
2.1 绿色溶剂的分类方法 3
2.2 绿色溶剂的环境影响评估 4
第3章 芳香族化合物的合成路径 6
3.1 传统合成方法概述 6
3.2 绿色溶剂在芳香族化合物合成中的应用潜力 6
3.3 绿色溶剂对合成效率的影响分析 7
第4章 绿色溶剂对芳香族化合物合成反应的影响 9
4.1 反应速率的变化 9
4.1.1 温度对反应速率的影响 9
4.1.2 溶剂极性对反应速率的影响 10
4.1.3 pH值对反应速率的影响 10
4.2 产物选择性的变化 11
4.2.1 不同绿色溶剂下的产物分布 11
4.2.2 催化剂类型对产物选择性的影响 12
4.2.3 反应条件优化对产物选择性的影响 13
第5章 绿色溶剂在工业生产中的应用前景与挑战 14
5.1 工业生产中的应用案例分析 14
5.2 面临的挑战与解决方案探讨 15
结 论 17
参考文献 18
致 谢 19
随着环保意识提升，绿色化学成为研究热点，特别是绿色溶剂在芳香族化合物合成中的应用。本研究探讨了水、离子液体和超临界二氧化碳等绿色溶剂对合成效率和产物纯度的影响，旨在为绿色化学提供理论和实践指导。研究发现，水在某些反应中反应速率和产物纯度较高，离子液体在特定反应中表现出优越性，而超临界二氧化碳在高温高压下能提高反应选择性和产率。优化反应条件和溶剂选择可减少副产物，提高经济性和环保性。研究还结合中国化工产业现状，提出适合国情的绿色溶剂应用策略，如推广水溶剂应用和推荐使用离子液体及超临界二氧化碳。这些策略有助于推动中国化工产业绿色转型和可持续发展。本研究揭示了不同绿色溶剂的优缺点和适用范围，为绿色化学发展提供新思路和方法，并结合中国实际提出的应用策略具有重要现实意义和推广价值。
关键词：绿色溶剂；芳香族化合物合成；可持续发展；离子液体；超临界二氧化碳
Abstract
With the promotion of environmental awareness, green chemistry has become a research hotspot, especially the application of green solvents in the synthesis of aromatic compounds. This study explored the effects of green solvents such as water, ionic liquids and supercritical carbon dioxide on the synthesis efficiency and product purity, aiming to provide theoretical and practical guidance for green chemistry. It is found that water has high reaction rate and product purity in some reactions, ionic liquid shows superiority in specific reactions, and supercritical carbon dioxide can improve the reaction selectivity and yield at high temperature and high pressure. Optimizing reaction conditions and solvent selection can reduce by-products and improve economy and environmental protection. In combination with the current situation of China's chemical industry, the research also puts forward green solvent application strategies suitable for national conditions, such as promoting the application of water solvent and recommending the use of ionic liquid and supercritical carbon dioxide. These strategies will help to promote the green transformation and sustainable development of China's chemical industry. This study reveals the advantages and disadvantages of application and application scope of different green solvents, provides new ideas and methods for the development of green chemistry, and the application strategies combined with China are of great practical significance and promotion value.
Key Words：Green solvent; Synthesis of aromatic compounds; Sustainable development; Ionic liquid; Supercritical carbon dioxide
目 录
摘 要 I
Abstract II
第1章 绪论 1
1.1 研究背景和意义 1
1.2 研究目的和内容 1
第2章 绿色溶剂的定义与分类 3
2.1 绿色溶剂的分类方法 3
2.2 绿色溶剂的环境影响评估 4
第3章 芳香族化合物的合成路径 6
3.1 传统合成方法概述 6
3.2 绿色溶剂在芳香族化合物合成中的应用潜力 6
3.3 绿色溶剂对合成效率的影响分析 7
第4章 绿色溶剂对芳香族化合物合成反应的影响 9
4.1 反应速率的变化 9
4.1.1 温度对反应速率的影响 9
4.1.2 溶剂极性对反应速率的影响 10
4.1.3 pH值对反应速率的影响 10
4.2 产物选择性的变化 11
4.2.1 不同绿色溶剂下的产物分布 11
4.2.2 催化剂类型对产物选择性的影响 12
4.2.3 反应条件优化对产物选择性的影响 13
第5章 绿色溶剂在工业生产中的应用前景与挑战 14
5.1 工业生产中的应用案例分析 14
5.2 面临的挑战与解决方案探讨 15
结 论 17
参考文献 18
致 谢 19
