摘 要
环境敏感型高分子材料因其对特定外界刺激（如温度、pH值、光、电场等）的响应性，在智能材料领域展现出广阔的应用前景。本研究旨在设计与制备一系列具有优异环境敏感性能的高分子材料，并探索其在药物递送、传感器及自修复材料等领域的潜在应用。通过引入功能性单体和交联剂，采用自由基聚合、RAFT聚合以及点击化学等先进合成方法，成功制备了多种响应性水凝胶、纳米粒子及薄膜材料。实验结果表明，所制备的材料在不同刺激条件下表现出显著的体积变化、溶胀行为或光学性质改变，且具有良好的可逆性和稳定性。特别是在pH响应性水凝胶中，通过调控网络结构参数实现了对特定pH范围的高度选择性响应，为酸碱失衡相关疾病的靶向治疗提供了新思路。此外，基于光响应型高分子的自修复涂层展现出快速高效的损伤修复能力，进一步验证了该类材料的实际应用价值。本研究不仅拓展了环境敏感型高分子材料的设计策略，还为其在生物医药和功能器件中的应用奠定了理论与实验基础，为未来智能材料的发展提供了重要参考。关键词：环境敏感型高分子；pH响应性水凝胶；光响应型高分子；药物递送；自修复材料
Abstract
Environmentally sensitive polymeric materials, which exhibit responsiveness to specific external stimuli such as temperature, pH, light, and electric fields, have demonstrated promising application prospects in the field of smart materials. This study focuses on the design and preparation of a series of polymeric materials with excellent environmental sensitivity, exploring their potential applications in drug delivery, sensors, and self-healing materials. By incorporating functional monomers and crosslinkers, advanced synthetic methods including free radical polymerization, RAFT polymerization, and click chemistry were employed to successfully fabricate various responsive hydrogels, nanoparticles, and film materials. The experimental results indicate that the prepared materials exhibit significant volume changes, swelling behavior, or optical property alterations under different stimuli, along with good reversibility and stability. Notably, in pH-responsive hydrogels, highly selective responses within specific pH ranges were achieved by adjusting network structural parameters, providing new insights for targeted treatments of acid-base imbalance-related diseases. Additionally, self-healing coatings based on photoresponsive polymers demonstrated rapid and efficient damage repair capabilities, further validating the practical application value of these materials. This research not only expands the design strategies for environmentally sensitive polymeric materials but also lays theoretical and experimental foundations for their applications in biomedicine and functional devices, offering crucial references for the future development of smart materials..Key Words：Environment-Sensitive Polymers；Ph-Responsive Hydrogels；Light-Responsive Polymers；Drug Delivery；Self-Healing Materials
目 录
摘 要 I
Abstract II
第1章 绪论 1
1.1 环境敏感型高分子材料的研究背景 1
1.2 环境敏感型高分子材料的应用意义 1
1.3 国内外研究现状与发展趋势 2
1.4 本文研究方法与技术路线 2
第2章 环境敏感型高分子材料的制备原理 3
2.1 高分子材料的基本特性分析 3
2.2 环境敏感响应机制研究 3
2.3 制备方法的选择与优化 4
2.4 关键影响因素探讨 4
2.5 制备过程中的挑战与解决方案 5
第3章 环境敏感型高分子材料的性能表征 6
3.1 材料结构与性能的关系分析 6
3.2 敏感响应性能测试方法 6
3.3 功能化改性对性能的影响 7
3.4 不同环境条件下的性能评估 7
3.5 性能优化的技术路径 8
第4章 环境敏感型高分子材料的应用探索 9
4.1 在智能器件中的应用前景 9
4.2 在生物医药领域的功能实现 9
4.3 在环境监测中的实际应用 10
4.4 在能源存储中的潜在价值 10
4.5 应用过程中面临的问题与对策 11
结 论 12
参考文献 13
致 谢 14
